Development and Characterization of Bioplastics from Straw and Rice Husk for: Effect of Addition of Glycerin, CMC, and TiO2
DOI:
https://doi.org/10.33394/hjkk.v12i6.13821Keywords:
bioplastic, rice straw, rice husk, glycerin, carboxymethyl cellulose (CMC), titanium dioxide (TiOâ‚‚)Abstract
The development of environmentally friendly materials is crucial to mitigate the environmental impact of conventional plastics. This study focuses on developing bioplastics using rice straw and rice husks, combined with glycerine, carboxymethyl cellulose (CMC), and titanium dioxide (TiO₂). Glycerine acts as a plasticizer to enhance flexibility, CMC functions as a matrix binder, and TiO₂ serves as a reinforcing agent to improve mechanical strength. Bioplastics were produced using the casting method with specific proportions of these materials. Characterization tests included scanning electron microscopy (SEM) for morphology, biodegradability tests, water absorption analysis, and tensile strength measurements. Results revealed that the combination of rice straw and rice husks produced bioplastics with varied morphologies. TiO₂ enhanced mechanical strength and material homogeneity, though its distribution requires further optimization. Glycerine significantly increased flexibility, while CMC improved matrix cohesion. The novelty of this research lies in the integration of agro-industrial waste—rice straw and rice husks—with TiO₂, glycerine, and CMC, creating bioplastics that balance biodegradability, mechanical properties, and flexibility. This innovative approach demonstrates the potential of utilizing agricultural byproducts to produce sustainable alternatives to conventional plastics, offering customizable properties for diverse applications.
References
Ali, S., Isha, & Chang, Y. C. (2023). Ecotoxicological Impact of Bioplastics Biodegradation: A Comprehensive Review. MDPI.
Amin, M., Chowdhury, M. A., & Kowser, M. (2019). Characterization and performance analysis of composite bioplastics synthesized using titanium dioxide nanoparticles with corn starch. Heliyon.
Ashgar, U., Nadeem, M., Irfan, M., Syed, Q., Nelofer, R., & Iram, M. (2015). Effect of NaOH on Deligniï¬cation of Saccharum spontaneum. Wiley Online Library , 1-5.
Bajpai, P. (2018). Pulping Fundamentals. In P. Bajpai, Biermann's Handbook of Pulp and Paper: Raw Material and Pulp Making (pp. 295-351). Elsevier.
Benitez, J., Florido, P. M., Vázquez, J. P., Tedeschi, G., Athanassiou, A., Heredia, J. G., & Puyol, S. G. (2024). Transparent, plasticized cellulose-glycerol bioplastics for food packaging applications. International Journal of Biological Macromolecules.
Berghuis, N. T., Mutmainah, D. K., Savitri, M. N., Arizki, M., Yunita, D. D., Awaluddin, F., . . . Bramasta, R. K. (2022). Bioplastic from Cassava peel and eggshell waste . Natural Science and Mathematics Research.
Cazan, C., Enesca, A., & Andronic, L. (2021). Synergic Effect of TiO2 Filler on the Mechanical Properties of Polymer Nanocomposites. Polymers.
Gerbie, B., Alemayehu, A., Belay, M., & Ewunetu, M. (2024). Water Absorption Reduction of Biodegradable Plastic Made From Sugar Cane Molasses by the Synergistic Effect of Sisal Fiber Reinforcement and Succinic Acid Crosslinking. Research Square.
Goodman, B. (2020). Utilization of waste straw and husks from rice production: A review. Journal of Bioresources and Bioproducts.
Han, C., Yuan, Z., Sun, B., Qiu, H., Huang, Y., & Zhang, M. (2024). Effects of carboxymethyl cellulose concentration on mechanical, viscoelastic properties, and thermal properties of starch/plant fiber foaming tableware materials with foam structure. Industrial Crops and Products.
Han, C., Yuan, Z., Sun, B., Qiu, H., Huang, Y., & Zhang, M. (2024). Effects of carboxymethyl cellulose concentration on mechanical, viscoelastic properties, and thermal properties of starch/plant fiber foaming tableware materials with foam structure. Elsevier.
Han, L., Feng, J., Zhang, S., Ma, Z., Wang, Y., & Zhang, X. (2012). Alkali pretreated of wheat straw and its enzymatic hydrolysis. Brazilian Journal of Microbiology, 53-61.
Michele, A. Ruiz, H., P. Silva, D., Ruzene, D., Teixeira, J., & Polizeli , M. L. (2015). Cellulose from Lignocellulosic Waste. Springer Nature, 475–511.
Mohammed, Rahman, R., Mohammed, A., Adam, T., Betar, B., Osman, A., & Dahham, O. (2022). Surface treatment to improve water repellence and compatibility of natural fiber with polymer matrix: Recent advancement. Elsevier.
Negrete, D. B., & Guerrero, V. (2024). Opportunities and Challenges in the Application of Bioplastics: Perspectives from Formulation, Processing, and Performance. Polymers.
Negrete-Bolagay, D., & Guerrero, V. (2024). Opportunities and Challenges in the Application of Bioplastics: Perspectives from Formulation, Processing, and Performance. MDPI.
Nuriyah, L., Saroja, G., Ghufron, M., Razanata, A., & Rosid, N. F. (2018). Tensile Strength and Elongation Characteristics of Bioplastics Made from Cilembu Sweet Potatoes Starch with Various Types of Plasticizers. Natural B.
Prasetia, I. J., Deviana, S., Damayanti, T., Cahyadi, A., & Agus Gelge, I. W. (2018). The effect of NaOH Concentration in Delignification Process on Microcrystalline Cellulose from Green Algae (Cladophora sp.) As The Renewable Marine Product. Jurnal Farmasi Sains dan Komunitas, 68-71.
Qin, C., Soykeabkaew, N., Xiuyuan, N., & Peijs, T. (2024). The effect of fibre volume fraction and mercerization on the properties of all-cellulose composites. Carbohydrate Polymer.
Ubaidah, A. A., Puad, N. M., Nor, Y. A., Hamzah, F., & Azmi, A. S. (2024). Synthesis of bioplastics and the effects of additives on the mechanical, thermal and biodegradable properties. Sage Journals.
Walawska, A., Olak-Kucharczyk, M., Kaczmarek, A., & H. Kudzin, M. (2024). Environmentally Friendly Bleaching Process of the Cellulose Fibres Materials Using Ozone and Hydrogen Peroxide in the Gas Phase. MDPI.
Wang, J.-X., Asano, S., Kudo, S., & Hayashi, J.-i. (2020). Deep Delignification of Woody Biomass by Repeated Mild Alkaline Treatments with Pressurized O2. ACS Omega.
Yang, X., Zhao, J., Liang, J., & Zhu, J. (2020). Efficient and Selective Catalytic Conversion of Hemicellulose in Rice Straw by Metal Catalyst under Mild Conditions. MDPI.
Zhao, X., Wang, Y., Chen, X., Yu, X., Li, W., Zhang, S., . . . Zhu, H. (2023). Sustainable bioplastics derived from renewable natural resources for food packaging. Matter.
Downloads
Published
How to Cite
Issue
Section
Citation Check
License
License and Publishing Agreement
In submitting the manuscript to the journal, the authors certify that:
- They are authorized by their co-authors to enter into these arrangements.
- The work described has not been formally published before, except in the form of an abstract or as part of a published lecture, review, thesis, or overlay journal.
- That it is not under consideration for publication elsewhere,
- That its publication has been approved by all the author(s) and by the responsible authorities – tacitly or explicitly – of the institutes where the work has been carried out.
- They secure the right to reproduce any material that has already been published or copyrighted elsewhere.
- They agree to the following license and publishing agreement.
Copyright
Authors who publish with Hydrogen: Jurnal Kependidikan Kimia agree to the following terms:
- Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License (CC BY-SA 4.0) that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal.Â
- Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
- Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.
Licensing for Data Publication
Hydrogen: Jurnal Kependidikan Kimia uses a variety of waivers and licenses, that are specifically designed for and appropriate for the treatment of data: Open Data Commons Attribution License, http://www.opendatacommons.org/licenses/by/1.0/ (default) Other data publishing licenses may be allowed as exceptions (subject to approval by the editor on a case-by-case basis) and should be justified with a written statement from the author, which will be published with the article.