Sintesis Metil Ester Nitrat dari Minyak Biji Nyamplung (Calophyllum inophyllum L)

Authors

  • Amal Astam Universitas Halu Oleo, Indonesia
  • Laily Nurliana Universitas Halu Oleo, Indonesia
  • La Ode Kadidae Universitas Halu Oleo, Indonesia

DOI:

https://doi.org/10.33394/hjkk.v7i2.1927

Keywords:

Methyl esters, degumming Esterification-Transesterification, Nitration, Nyamplung and FTIR

Abstract

Research on the synthesis of methyl ester nitrate from nyamplung seed oil (Calophyllum inophyllum L.). The aims of study are to are to determine the nitrate methyl ester can be synthesized from nyamplung seed oil determine the yield of the transesterification and nitration reaction from nyamplung seed oil. In this study nyamplung seed oil was obtained from pressing nyamplung seeds using a hydraulic press, then the crude oil obtained was subsequently degumming to remove gum. Free oil of the etherified gum then transesterification with methanol. The transesterification results are then titrated and produce nitric methyl esters. Characterization of nitric methyl ester  by spectrophotometer IR shows functional groups C-ONO2, C=C dan C-NO2 at wave number 1635,64 cm-1 1550,77 cm-1 dan 1365, 60 cm-1. The yield of transesterification of nyamplung oil was 64.66% and the nitration yield was 10.6%.

Author Biographies

Amal Astam, Universitas Halu Oleo

Jurusan Kimia

Laily Nurliana, Universitas Halu Oleo

Jurusan Kimia, FMIPA, Universitas Halu Oleo

La Ode Kadidae, Universitas Halu Oleo

Jurusan Kimia, FMIPA, Universitas Halu Oleo

References

Abdullah, Wicaksono, D. R., Junaidi, A.B., dan Badruzsaufari. 2010. Production Of Cetana Improfer From Jathropa Curcas Oil. Indo. J. Chem, 10 (3): 396-400.

Abdullah., Triyono., Trisunaryanti, W., and Haryadi W. 2016. Purification Of Methyl Ricinoleate On Producing Of Cetane Improver. J. Phys.824: 1-6.

Alamsyah, R., dan Lubis, E. H. 2012. Pengolahan Biodiesel Dari Biji Nyamplung (Calophyllum inophyllum L.) Dengan Cara Purifikasi Kering. Balai Besar Industri Agro (BBIA). 2(4). 61-72.

Arita, S., Afrianto, I., dan Fitriana, Y. 2008. Produksi Biodiesel Dari Minyak Jelantah Dengan Menggunakan Reaksi 2 Tahap (Esterifikasi Dan Transesterifikasi). Jurnal Teknik Kimia. 15(4): 57-65.

Aufar, A., dan Hendra, K. R. 2017. Sintesis Metil Ester Nitrat Sebagai Aditif Bahan Bakar Solar Untuk Meningkatkan Angka Setana (CN). Jurusan Teknik Kimia. ITS.

Cahyono, E., dan Siti, T. 2014. Pengaruh Penam bahan Aditif Alkil Nitrat Yang Disintesis Dari Biodiesel Minyak Biji Kapuk (Ceiba Petandra) Terhadap Kenaikan Angka Setana Solar. UNESA. Journal Of Chemistry. 3(1): 70-77.

Canoira, L., Ramon, A., Susana, T., Nikolaos, Eviripidis, L., and Dimitrios, M. K. 2007. Nitration Of Biodiesel Of Waste Oil: Nitrated Biodiesel As A Cetane Number Enhancer. Science Direct. 86: 965-971.

Damayanti, A. 2011. Pengolahan Biji Mahoni (Swietenia Macrophylla King) sebagai Bahan Baku Alternatif Biodiesel. Jurnal Bahan Alam Terbarukan. 1(1): 8-15.

Hasahatan, D., Sunaryo, J., dan Komariah, L. N. 2012. Pengaruh Ratio H2SO4 dan Waktu Reaksi Terhadap Kuantitas dan Kualitas Biodiesel Dari Minyak Jarak Pagar. Jurnal Teknik Kimia. 2(18) : 26-36.

Hasibuan, S., Sahirman, dan Yudawati, N. M. A. 2013. Karakteristik Fisikokimia dan Antibakteri Hasil Purifikasi Minyak Biji Nyamplung (Calophyllum inophyllum L.). Agritech, 33(3): 311-319.

Hikmah, M. N., dan Zuliyana. 2010. Pembuatan Metil Ester (Biodiesel) dari Minyak Dedak dan Metanol dengan Proses Esterifikasi dan Transesterifikasi.Skripsi. Fakultas Teknik. UNDIP: Semarang.

Leksono, B., Hendrati,R. L., Mashudi, Windyarini, E., dan Hasnah, T. M. 2012. Pemuliaan Nyamplung (Calophyllum inophyllum L.) untuk Bahan Baku Biofuel.Yogyakarta: Balai Besar Penelitian Bioteknologi.

Muderawan, I. W., dan Ni Ketut, P. D., 2016. Pembuatan Biodiesel Dari Minyak Nyamplung (Calophyllum Inophyllum l.) dan Analisis Metil Esternya Dengan GC-MS. PSN FMIPA. ISBN 978-602-6428-00-4.

Muhammad, F. R., Jatranti, S., Qadariyah, L., dan Mahfud. 2014. Pembuatan Biodiesel dari Minyak Nyamplung menggunakan Pemanasan Gelombang Mikro. Jurnal Teknik Pomits. 3(2): 2301-9271.

Musta, R., Haetami, A., dan Salmawati, M. 2017. Biodiesel Hasil Transesterifikasi Minyak Biji Nyamplung (Calophyllum Inophyllum l.) Dengan Metanol. JTM. 4(2): 394-401.

Nasikin, M., dan Ade, M. 2003. Sintesis Metil Ester Sebagai Aditif Bahan Bakar Solar Dari Minyak Sawit. Jurnal Teknologi. 1(27): 45-50.

Nurhayati. 2014. Bahan Ajar Siswa Teknologi Pemrosesan Biodisel. Bandung: Etc Foundation The Netherlands. 23-30.

Prihanto, A., Pramudono, B., dan Santosa, H. 2013. Peningkatan Yield Biodiesel dari Minyak Biji Nyamplung melalui Transesterifikasi Dua Tahap.Jurnal Momentum. 9(2): 46-53.

Putra, N. E., dan Sungkono, H. D. K. 2012. Uji Eksperimental Bahan Bakar campuran Biosolar Dengan Zat Aditif Terhadap Unjuk Kerja Motor Disel Putaran Konstan. Jurnal Teknis POMITS. 1(1): 1-5.

Rufaida, A. D., dan Waldjinah. 2012. Pegangan Guru Kimia Kelas X SMA/MA. Klaten: Intan Pariwara.

Siburian, A. M., Pardede, A. S. D., dan Pandila, S. 2014. Pemanfaatan Adsorben dari Biji Jawa untuk Menurunkan Bilangan peroksida pada CPO (Crude Palm Oil). Jurnal Teknik Kimia USU. 3(4): 65-73.

Stratiev, D., Rinkov, R., Petkov, K., dan Stanulov. 2010 Evaluation of Crude Oil Quality. Petrol Coal. 1 : 35-43.

Downloads

Published

2020-01-10

How to Cite

Astam, A., Nurliana, L., & Kadidae, L. O. (2020). Sintesis Metil Ester Nitrat dari Minyak Biji Nyamplung (Calophyllum inophyllum L). Hydrogen: Jurnal Kependidikan Kimia, 7(2), 82–90. https://doi.org/10.33394/hjkk.v7i2.1927

Issue

Vol. 7 No. 2 (2019): Hydrogen: Jurnal Kependidikan Kimia

Section

Articles

Citation Check

License

License and Publishing Agreement
In submitting the manuscript to the journal, the authors certify that:

  1. They are authorized by their co-authors to enter into these arrangements.
  2. The work described has not been formally published before, except in the form of an abstract or as part of a published lecture, review, thesis, or overlay journal.
  3. That it is not under consideration for publication elsewhere,
  4. That its publication has been approved by all the author(s) and by the responsible authorities – tacitly or explicitly – of the institutes where the work has been carried out.
  5. They secure the right to reproduce any material that has already been published or copyrighted elsewhere.
  6. They agree to the following license and publishing agreement.

Copyright
Authors who publish with Hydrogen: Jurnal Kependidikan Kimia agree to the following terms:

  1. Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License (CC BY-SA 4.0) that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this journal. 
  2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial publication in this journal.
  3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work.

Licensing for Data Publication

Hydrogen: Jurnal Kependidikan Kimia uses a variety of waivers and licenses, that are specifically designed for and appropriate for the treatment of data: Open Data Commons Attribution License, http://www.opendatacommons.org/licenses/by/1.0/ (default) Other data publishing licenses may be allowed as exceptions (subject to approval by the editor on a case-by-case basis) and should be justified with a written statement from the author, which will be published with the article.