PENGARUH PERBANDINGAN KONSENTRASI TBP : D2EHPA DAN KONSENTRASI PENGEMBAN DALAM FASAORGANIK PADA EKSTRAKSI PERAK DARI LIMBAH FOTO ROENTGEN

Authors

  • Novita Rusmayanti Andika Putri IKIP Mataram, Indonesia
  • Yeti Kurniasih IKIP Mataram, Indonesia
  • Ahmadi Ahmadi IKIP Mataram, Indonesia

DOI:

https://doi.org/10.33394/hjkk.v4i2.92

Keywords:

Solvent Extraction, Photo Roentgen waste, D2EHPA, TBP

Abstract

Photo roentgen used for examination of internal organs can produce wastes that are harmful to health and the environment because they containing silver metal ion(Ag+) inform of silver thiosulfate complex ([Ag(S2O3)2]-3). Therefore it was necessary for the separation of Ag metal so that the metal does not pollute the environment and can be used economically. One way to separate the metal Ag is by solvent extraction techniques. This study aimed to determine the effect of concentration ratio of TBP:D2EHPA and carrier compound concentration in the organic phase of the percent extraction of silver metal then applied to the sample photo roentgen waste. Extraction of the metals Ag done by varying the ratio of the combined carrier concentration of TBP and D2EHPA in kerosene by concentration ratio was 0: 1; 0.25: 0.75; 0.5: 0.5; 0.75: 0.25 and 1: 0 M as well as by varying the carrier concentration in the organic phase ranging from 0 M; 0.5 M; 1 M and 1.5 M. Measuring the concentration of metal ions Ag+in water phase before and after extraction was determined by atomic absorptionspectrophotometer (AAS) at a wavelength of 328,22 nm then calculated percent extraction. Based on the research that obtained the highest percent extraction on single used carrier compounds and compound concentration carrier D2EHPA in optimum water was 0.5 M with 58.22% percent extraction. Applications optimum conditions to the extraction of silver metal obtained from photo roentgenwaste percent extraction was 10.27%.

Author Biographies

Novita Rusmayanti Andika Putri, IKIP Mataram

Program Studi Pendidikan Kimia

Yeti Kurniasih, IKIP Mataram

Program Studi Pendidikan Kimia

Ahmadi Ahmadi, IKIP Mataram

Program Studi Pendidikan Kimia

References

De, A. K., Khopkar S.M. dan Chalmers R.A.,. 1970. Solvent extraction of Metal. Van Nostrand Reinhold, London, pp.164-174.

Djunaidi, M.C., dan Gunawan. 2006. “Ekstraksi Zn (II) dan Cu (II) dengan Ekstraktan Di-2-Ethylhexyl Phosphate Acid-Tri Buthyl Phosphateâ€. J.Alchemy, Vol. 5, No. 1 Hal : 60-67. ISSN 1412-4092.

Djunaidi, M.C., dkk. 2007. “Recovery Perak dari Limbah Fotografi Melalui Membran Cair Berpendukung dengan Senyawa Pembawa Asam Di-2-Etil Heksilfosfat (D2EHPA)â€. Reaktor,Vol.11 No.2 Hal : 98-103.

Fitria, Linda. 2011. “Recovery Logam Perak (Ag) Dari Limbah Foto Roentgen Dengan Menggunakan Teknik Membran Cair Emulsi Menggunakan Senyawa Pengemban Tri Butil Fosfatâ€. Skripsi, IKIP Mataram, Mataram.

Hadikawuryan, D.S. 2005. “Pemisahan Logam Perak (I) Menggunakan Membran Cair Emulsi (ELM) dengan Pembawa Sinergiâ€. Skripsi, Universitas Diponegoro, Semarang.

Kurniasih, Yeti., dkk. 2012. “ Pemisahan Logam Perak Dari Limbah Foto Roentgen Dengan Teknik Ekstraksi Pelarut Menggunakan Senyawa Pengemban TBP dan D2EHPA (Implementasi Pembelajaran Mata Kuliah Pemisahan Analitik) “. Prosiding Seminar Nasional Sains 2012 Reorientasi Pembelajaran Sains.

Santoso., Imam dan Buchori. 2010. “Pengaruh Matriks Terhadap Persen Ekstraksi Perak (I) Dari Limbah Cuci/Cetak Foto Dengan Menggunakan Teknik Pemisahan Emulsi Membran Cairâ€. Indonesian Journal Of Chemistry.

Sugiyono. 2015. Metode Penelitian Kualitatif, Kuantitatif, R & D. Bandung : Alfabeta.

Tri Wahyuningsih, Nita. 2011. “ Recovery Logam Perak (Ag) Dari Limbah Foto Roentgen Dengan Menggunakan Teknik Ekstraksi Pelarut Menggunakan Senyawa Pengemban Tri Butil Fosfatâ€. Skripsi, IKIP Mataram, Mataram.

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Published

2016-12-17

How to Cite

Andika Putri, N. R., Kurniasih, Y., & Ahmadi, A. (2016). PENGARUH PERBANDINGAN KONSENTRASI TBP : D2EHPA DAN KONSENTRASI PENGEMBAN DALAM FASAORGANIK PADA EKSTRAKSI PERAK DARI LIMBAH FOTO ROENTGEN. Hydrogen: Jurnal Kependidikan Kimia, 4(2), 87–93. https://doi.org/10.33394/hjkk.v4i2.92

Issue

Vol. 4 No. 2 (2016): Hydrogen: Jurnal Kependidikan Kimia

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Articles

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