Synergetic Effect of Potassium Iodide and Miana (Coleus scutellaroides (L.) Benth.) Leaves Extract on Mild Steel in HCl Medium

Authors

  • Sanaq Elfira Putri Andalas University, Indonesia
  • Vira Anggita Gusniardi Andalas University, Indonesia
  • Suryati Suryati Andalas University, Indonesia
  • Emriadi Emriadi Andalas University, Indonesia

DOI:

https://doi.org/10.33394/hjkk.v11i6.9810

Keywords:

mild steel, corrosion inhibition, Miana leaves extract, potassium iodide, synergistic effects, FTIR, SEM

Abstract

Due to its low carbon content, mild steel is prone to corrosion. Therefore, corrosion inhibitors are needed to decrease the corrosive rate of mild steel. This research aims to investigate the influence of adding potassium iodide to miana leaves extract (Coleus scutellaroides (L.) Benth.) (MLE) on the corrosion rate of mild steel, identify the type of adsorption, synergistic effects and characterize the surface of mild steel both before and after the addition of potassium iodide. The weight loss method is employed to test the corrosion rate, and the type of adsorption is identified through thermodynamic calculations. Surface characterization is evaluated using Fourier Transform Infrared (FTIR) and Scanning Electron Microscopy (SEM). As potassium iodide is added, the weight loss findings show an increase in inhibitory efficiency. When potassium iodide concentration was 0.4 g/L and temperature was 30°C, the maximum inhibitory efficiency was attained, which was 92.784%. Characterization analysis indicates the interaction between potassium iodide and MLE with the surface of mild steel. This research has not been explored yet and is expected to provide information on the use of potassium iodide and MLE as environmentally friendly corrosion inhibitors.

Author Biographies

Sanaq Elfira Putri, Andalas University

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Vira Anggita Gusniardi, Andalas University

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Suryati Suryati, Andalas University

Department of Chemistry, Faculty of Mathematics and Natural Sciences

Emriadi Emriadi, Andalas University

Department of Chemistry, Faculty of Mathematics and Natural Sciences

References

Astuti, A. D., Perdana, A. I., Natzir, R., Massi, M. N., Subehan, & Alam, G. (2021). Compound Analysis And Genetic Study Of Selected Plectranthus scutellarioides Varieties From Indonesia. Pharmacognosy Journal, 13(6), 1516–1526. https://doi.org/10.5530/PJ.2021.13.193

Astuti, A. D., Yasir, B., Subehan, & Alam, G. (2019). Comparison Of Two Varieties Of Plectranthus scutellarioides Based On Extraction Method, Phytochemical Compound, And Cytotoxicity. Journal of Physics: Conference Series, 1341(7). https://doi.org/10.1088/1742-6596/1341/7/072012

Benghalia, M. A., Fares, C., Khadraoui, A., Meliani, M. H., Suleiman, R. K., Sorour, A. A., Dmytrakh, I. M., & Azari, Z. (2019). Assessment Of Corrosion Inhibitory Effect Of Ruta chalepensis Flavonoid Extracts On API 5L X52 Steel In 1M HCL Medium. Environmental Engineering and Management Journal, 18(9), 2009–2021. https://doi.org/10.30638/eemj.2019.191

Bhardwaj, N., Sharma, P., & Kumar, V. (2021). Phytochemicals as steel corrosion inhibitor: An insight into mechanism. Corrosion Reviews, 39(1), 27–41. https://doi.org/10.1515/corrrev-2020-0046

Chapagain, A., Acharya, D., Das, A. K., Chhetri, K., Oli, H. B., & Yadav, A. P. (2022). Alkaloid of Rhynchostylis retusa as Green Inhibitor for Mild Steel Corrosion in 1 M H2SO4 Solution. Electrochem, 3(2), 211–224. https://doi.org/10.3390/electrochem3020013

Djellab, M. (2018). Synergistic Effect Of Halide Ions And Gum Arabic For The Corrosion Inhibition Of API5L X70 Pipeline Steel In H2SO4. Materials and Corrosion, July, 1–12. https://doi.org/10.1002/maco.201810203

El-katori, E. E., Fouda, A. S., & Mohamed, R. R. (2020). Synergistic Corrosion Inhibition Activity Of The Chicoriumintybus Extract And Iodide Ions For Mild Steel In Acidic Media. Journal of the Chilean Chemical Society, 65(1), 4672–4681. https://doi.org/10.4067/S0717-97072020000104672

Emembolu, L., & Igwegbe, C. (2022). Investigation of Temperature Correlations on Corrosion Inhibition of Carbon Steel in Acid Media by Flower Extract. European Journal of Engineering and Applied Sciences, 5(1), 29–36. https://doi.org/10.55581/ejeas.1127813

Emriadi, Untari, P., & Efdi, M. (2021). Leave extract of syzygium malaccenseas green inhibitor of mild steel in acidic medium. Rasayan Journal of Chemistry, 14(1), 569–577. https://doi.org/10.31788/RJC.2021.1415836

Emriadi, Yulistia, V., & Aziz, H. (2018). Corrosion Inhibition of Mild Steel in Hidrochloric Acid Solution by Gnetum gnemon . L Peel Extract as Green Inhibitor. Der Pharma Chemica, 10(10), 79–85.

Febriani, A., Umaro, S. A., Nursa’adah, E., & Firdaus, M. L. (2022). Kapasitas Adsorpsi Zat Warna Malachite Green Dan Violet Dye Menggunakan Metal Organic Frameworks (Fe-BDC). Hydrogen : Jurnal Kependidikan Kimia, 10(2), 61–72. http://ojs.undikma.ac.id/index.php/hydrogen/

Indah, D. R., & Safnowandi, S. (2020). Karakterisasi Karbon Baggase Teraktivasi dan Aplikasinya untuk Adsorpsi Logam Tembaga. Hydrogen: Jurnal Kependidikan Kimia, 7(2), 46. https://doi.org/10.33394/hjkk.v7i2.1912

Khadiri, M., Idouhli, R., Bennouna, M. A., Aityoub, A., Abouelfida, A., & Benyaïch, A. (2021). Contribution To Understanding Synergistic Effect Of Punica Granatum Extract And Potassium Iodide As Corrosion Inhibitor Of S355 Steel. Corrosion Reviews, 39(2), 137–148. https://doi.org/10.1515/corrrev-2020-0042

Khadom, A. A., Abd, A. N., & Ahmed, N. A. (2022). Synergistic effect of iodide ions on the corrosion inhibition of mild steel in 1 M HCl by Cardaria Draba leaf extract. Results in Chemistry, 4, 0–6. https://doi.org/10.1016/j.rechem.2022.100668

Khadom, A. A., Abd, A. N., & Arif, N. (2018). Potassium Iodide as a Corrosion Inhibitor of Mild Steel in Hydrochloric Acid: Kinetics and Mathematical Studies. Journal of Bio- and Tribo-Corrosion, October. https://doi.org/10.1007/s40735-018-0133-4

Marzorati, S., Verotta, L., & Trasatti, S. P. (2019). Green Corrosion Inhibitors from Natural Sources and Biomass Wastes : Review. MDPI, 1–24. https://doi.org/10.3390/molecules24010048

Ogunleye, O. O., Arinkoola, A. O., Eletta, O. A., Agbede, O. O., Osho, Y. A., Morakinyo, A. F., & Hamed, J. O. (2020). Green Corrosion Inhibition And Adsorption Characteristics Of Luffa Cylindrica Leaf Extract On Mild Steel In Hydrochloric Acid Environment. Heliyon, 6(1), 1–12. https://doi.org/10.1016/j.heliyon.2020.e03205

Pramudita, M., Sukirno, S., & Nasikin, M. (2019). Synergistic Corrosion Inhibition Effect Of Rice Husk Extract And KI For Mild Steel In H2SO4 Solution. Bulletin of Chemical Reaction Engineering &Amp; Catalysis, 14(3), 697–704. https://doi.org/10.9767/bcrec.14.3.4249.697-704

Priya, V. S., Rani, C. U., & Velrani, S. (2018). Synergistic Effect Of Halide Ions On The Corrosion Inhibition Of Mild Steel In Sulphuric Acid Using Methyl, N-Methyl Ethyl and Ethyl Substituted γ -2,c-6-Diphenyl Piperidin-4-One Semicarbazones. Surface Review and Letters, 25(2), 1–9. https://doi.org/10.1142/S0218625X18500506

Riastuti, R., Setiawidiani, D., Soedarsono, J. W., Aribowo, S., Paul, A., & Kaban, S. (2022). Development Of Saga (Abrus Precatorius ) Seed Extract As A Green Corrosion Inhibitor In API 5L Grade B Under 1M HCl. Eastern-European Journal of Enterprise Technologies, 6, 46–56. https://doi.org/https://doi.org/10.15587/1729-4061.2022.263236

Sait, N., Aliouane, N., Ahmed, N. A., Toukal, L., & Al-, M. (2021). Synergistic Effect Of Potassium Iodide On Corrosion Inhibition Of Copper By Tetraphosphonic Acid In Hydrochloric Acid Solution. Journal of Adhesion Science and Technology, 0(0), 1–25.

Salimi, Y. K. (2021). Daun Miana Sebagai Antioksidan & Antikanker. In Angewandte Chemie International Edition, 6(11), 951–952. IKAPI.

Saraswat, V., & Yadav, M. (2021). Improved corrosion resistant performance of mild steel under acid environment by novel carbon dots as green corrosion inhibitor. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 627(April), 127172. https://doi.org/10.1016/j.colsurfa.2021.127172

Shamnamol, G., Jacob, J. M., & Rugma, P. (2020). Synergistic effect of salts on the corrosion inhibitive action of plant extract : a review. Journal of Adhesion Science and Technology, 0(0), 1–31. https://doi.org/10.1080/01694243.2020.1797336

Stiadi, Y., Rahmayeni, Rahmawati, L., Efdi, M., Aziz, H., & Emriadi. (2020). Mangifera Odorata Griff Seed Extract As Corrosion Inhibitor Of Mild Steel In Hydrochloric Acid Medium. Rasayan Journal of Chemistry, 13(1), 230–239. https://doi.org/10.31788/RJC.2020.1315325

Thakur, A., & Kumar, A. (2021). Sustainable Inhibitors for Corrosion Mitigation in Aggressive Corrosive Media: A Comprehensive Study. In Journal of Bio- and Tribo-Corrosion (Vol. 7, Issue 2). Springer International Publishing. https://doi.org/10.1007/s40735-021-00501-y

Untari, P., Emriadi, Efdi, M., & Azuxetullatif. (2020). Efek Sinergetik Ekstrak Daun Jambu Bol (Syzygium malaccense) dan Iodida terhadap Korosi Baja dalam Larutan Asam. Chempublish Journal, 5(2), 179–193. https://doi.org/10.22437/chp.v5i2.11348

Verma, D. K., Khan, F., & Agrawal, S. (2017). Inhibition Effect of Bombax ceiba Flower Extract as Green Corrosion Inhibitor of Mild Steel in 0.5 M H2SO4 Medium. ASIAN JOURNAL OF CHEMISTRY, 29(12), 2615–2618. https://doi.org/https://doi.org/10.14233/ajchem.2017.20718

Wahyuni, S., Emriadi, & Suryati. (2022). Ekstrak Daun Kecapi Sebagai Inhibitor Korosi Baja Dalam Medium Asam Klorida. Jurnal Katalisator, 7(1), 41–51. https://doi.org/10.22216/jk.v5i2.5717

Wan, S., Chen, H., Zhang, T., Liao, B., & Guo, X. (2021). Anti-Corrosion Mechanism of Parsley Extract and Synergistic Iodide as Novel Corrosion Inhibitors for Carbon Steel-Q235 in Acidic Medium by Electrochemical, XPS and DFT Methods. Frontiers in Bioengineering and Biotechnology, 9(December 2021), 1–15. https://doi.org/10.3389/fbioe.2021.815953

Wijayanti, D. K., Fadly, D., Muharini, R., Rasmawan, R., Education, C., & Program, S. (2023). Inhibition of α -Glucosidase Enzyme by Ethanol Extract of Kratom Leaf Variant ( Mitragyna speciosa Korth.). HYDROGEN: Jurnal Kependidikan Kimia, 11(June).

Zaher, A., Aslam, R., Lee, H. S., Khafouri, A., Boufellous, M., Alrashdi, A. A., El aoufir, Y., Lgaz, H., & Ouhssine, M. (2022). A combined computational & electrochemical exploration of the Ammi visnaga L. extract as a green corrosion inhibitor for carbon steel in HCl solution. Arabian Journal of Chemistry, 15(2), 103573. https://doi.org/10.1016/j.arabjc.2021.103573

Zakeri, A., Bahmani, E., & Aghdam, A. S. R. (2022). Plant extracts as sustainable and green corrosion inhibitors for protection of ferrous metals in corrosive media: A mini review. Corrosion Communications, 5, 25–38. https://doi.org/10.1016/j.corcom.2022.03.002

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Published

2023-12-20

How to Cite

Putri, S. E., Gusniardi, V. A., Suryati, S., & Emriadi, E. (2023). Synergetic Effect of Potassium Iodide and Miana (Coleus scutellaroides (L.) Benth.) Leaves Extract on Mild Steel in HCl Medium. Hydrogen: Jurnal Kependidikan Kimia, 11(6), 835–845. https://doi.org/10.33394/hjkk.v11i6.9810

Issue

Vol. 11 No. 6 (2023): December 2023

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